离子-分子流体的统计场论

English | 2024 | ISBN: 978-3-031-68364-0 | 298 pages | True EPUB PDF | 39 MB

This book presents statistical physics methods based on self-consistent field theory for describing the thermodynamic properties of ion-molecular systems, including electrolyte solutions, ionic liquids, polymeric ionic liquids, and metal-organic complexes. The methods are applicable in both the bulk and at interfaces, taking into account the molecular structure of these systems. The book also provides a comprehensive analysis of the current state of art on statistical field theory for ion-molecular systems. It is primarily intended for researchers and graduate students in physical chemistry and condensed matter physics, as well as for physical chemists, physicists, and engineers interested in molecular system theory and simulation. By presenting these approaches, the book aims to enable readers to solve various problems in physical chemistry and electrochemistry using the methods described. The authors attempted to focus on specific issues and provide the necessary theoretical background. The book includes a mathematical introduction that readers can consult if they need clarification on any mathematical concepts or details omitted in the main text. In order to read the book, it is recommended that readers have a basic understanding of calculus, linear algebra, and probability theory, which can be acquired through standard university courses.

这本书基于自洽场论提出了描述离子分子系统热力学性质的统计物理学方法，包括电解质溶液、离子液体、聚合离子液体和金属-有机配合物。这些方法适用于整体以及界面，并考虑到这些系统的分子结构。此外，本书还提供了关于离子分子系统统计场论当前状态的全面分析。该书主要面向物理化学与凝聚态物理的研究人员及研究生，以及对分子系统理论与模拟感兴趣的物理化学家、物理学家和工程师。通过介绍这些方法，旨在使读者能够运用书中描述的方法解决物理学及电化学中的各种问题。作者力求聚焦具体问题并提供必要的理论背景知识。本书包含了一本数学简介，供需要更多数学概念或省略的细节解释的读者参考。为了阅读这本书，建议读者具备微积分、线性代数和概率论的基本理解，这些可以通过标准大学课程获得。

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